CN208802861U - Based on ozone-ULTRASONIC COMPLEX ...

Based on ozone-ULTRASONIC COMPLEX technology ecological water body wisdom managing and control system

Technical field

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The utility model belongs to the water treatment technology of environment protection field, in particular to based on the life of ozone-ULTRASONIC COMPLEX technology State water body wisdom managing and control system.

Background technique

The dynamic that all ecologies being stabilized are all based on substance diversity and influence each other and act between them Balance, ecological water body are naturally no exception.The ecological water body of the ecological balance be in water body various animal and plant, microorganism with other Non-life body substance with mutually eat and eaten, absorbed and absorbed nutrition relationship balance.The intracorporal ecological balance of ecological water is not Only influenced by biologies a variety of inside ecological water body and substances, also by overall situation biology except water body migrate into substance into Impact and influence out.

The control of ecological water body, core content are exactly the control of " ecological balance ", i.e., in ecological water body because internal and extraneous When reason causes the capacity of life and non-life body to be more than ecological water body autogenous control ability, lead to before and after ecology collapse The mode manually managed is crossed, increases and decreases the quantity of various biologies and substance with technological means to facilitate or rebuild the ecological balance.But For a long time, water treatment field in project management and in technical application always all without circle of good definition divide ecological water body manage and The two are related but have the concept of very big difference to industrial or agricultural stain disease purified treatment for life.

Life and industrial or agricultural stain disease purified treatment primarily to reach country formulation a series of water discharge standards, and Whether the water of these qualified discharges is suitble to the water quality requirement of ecological water body under the conditions of specific region, time and weather not Have and is paid attention to.Cause this phenomenon historical reasons be China pollution entering the water most it is noticeable be from life and industrial or agricultural The stain disease of production allows management organizations and research and development department at different levels to have to handle simultaneously because capital investment and technological accumulation are insufficient It focuses on this kind of stain disease.Secondly as both being located using almost the same physics, chemistry and biological principle Manage the substances such as organic and inorganic, microorganism in water, i.e., be nothing more than redox, degradation is decomposed, filtering is removed, precipitating aggregation and The technologies such as biocidal wash (combination) approach, it is easy to cause it is a kind of the former is handled well, ecological water body can also be managed Cognition, from idea using water quality to human body " clean harmless " as the highest goal of water process.This " highest goal " is aobvious So defective, the plain example closest to life is clean harmless domestic running water, cannot be used directly to the fish jar of family Change water.

The processing technique means of current main ecological water body specifically include that (1) diversion substitute mode: by external cleaning Water resource inputs ecological water body, reduces various pollutants concentration in ecological water body.This method must have sufficient clean water Make to guarantee in source.The major defect of diversion substitute mode is limited by mating water resource, facility and policy.(2) circulating filtration side Formula: in needing the water body that purifies, according to the size of ecological water body and the pollution that may be faced, pipe needed for mating circulating filtration The facilities such as line, electric appliance, filter material.Circulating filtration can eliminate the solid impurity in water and beautifying water body, but to endangering in ecological water body The maximum chemical pollutant of evil and microorganism, which are poisoned, then to be acted on without elimination.(3) it adds chemical agent: being a kind of short, adaptable and fast life State water body processing technique means can suit the remedy to the case for different pollution conditions, can quickly and easily take effect.Launch chemical drugs Though agent can be such that ecological purification of water quality beautifies whithin a period of time, over time, the harmful organism in water can generate drug resistance, The efficiency of chemical agent can decline, and interval is shortened, and injected volume increases.For the ecological water body of chronic pollution, long-term delivering medicament The ecological balance must be destroyed to the secondary pollution of environment with new pollution problem.(4) biological and ecological recovery technique: it is Using artificially launching or cultivating beneficial biotic population, ecological water pollutant is converted and degraded, to make water body Water quality is restored.This technology is a kind of reinforcing of nature recovery capability and self-purification capacity, is grinding for current environmental protection technology Study carefully exploitation hot spot.Because enabling beneficial biotic population to survive and playing the effect of purification beautifying water body, it still be unable to do without essence The heart safeguards these ecological water body environment effectively survived beneficial to population, with nature and artificially broken with the daily management problem that this is faced Bad ecological water body factor is without difference.In addition, time length, the low efficiency of biological and ecological reparation, generally require huge buffering and store Pond is to meet restoration of the ecosystem necessary time and space.(5) dredging draws mud method dredging and draws mud French for ecological to routed Or " subsequent regulation " means of going to war that the ecological water body in routed edge of running quickly carries out, though certain water cleaning can be restored in short term It is required that but this post is not avoided that ecological water body collapses again --- because again destroy the ecological balance inside and outside item Part one is not all reduced.

It is well known that current ecological water body eutrophication is that ammonia nitrogen in ecological water body and phosphorus are excessively high the main reason for out of control, Its source is widely used diammonium hydrogen phosphate (NH4)2HPO4.Diammonium hydrogen phosphate is the products such as electronics, medicine, fire-fighting fire retardant Important source material, and be more widely used as one of the main chemical fertilizer of agricultural, i.e. phosphorus-ammonium compound fertilizer.Meanwhile in aquaculture also Use it as feed addictive.Diammonium hydrogen phosphate is soluble easily in water, can with earth's surface, the convection current of underground water, infiltration and enter ecology Water body.Diammonium hydrogen phosphate generates ammonia (NH in water3·H2) and phosphate radical (including PO O4 3-Phosphate radical, PO3 2-Orthophosphite PO2- Hypophosphorous acid root).Eliminate one of the biggest problem that the phosphorus in ecological water body is always water body purification.

Once there is public technology using calper calcium peroxide mineralising phosphate radical, and generated insoluble (indissoluble) in the calcium phosphate of water and eliminate water Phosphorus in body.But calper calcium peroxide CaO2, be white odorless crystalline powdered inorganic object, in water body only and inorganic matter Chemical combination, needing the phosphate radical being eliminated that would not go contention with other organic matters in this way, chemical combination --- phosphoric acid can largely be adsorbed by having The organic matter of root goes back other gas chromatographies in adsorbed water body, so that eliminating phosphate radical just as can not only absorb phosphate radical Effect is seriously impaired and cannot be used for the practical application of ecological water body phosphorus content control.In addition, diammonium hydrogen phosphate be ammonia nitrogen and Phosphorus has the substance of fixed proportion, is decomposed into ammonia and phosphate radical in aqueous solution, if phosphate radical be mineralized as calcium phosphate and substantially Degree reduces content, while ammonium (NH4OH, that is, NH3·H2O) carbon dioxide of He Shuizhong again with the calcium ion in calper calcium peroxide The calcium carbonate hard to tolerate in water is produced, OH has been released-Water pH value is increased, leads to have broken ammonia nitrogen and phosphorus in ecological water body Balance.Ammonia nitrogen ratio increases substantially, and consequence is exactly that the fish and shrimp in ecological water body may meet with molecules of ammonia and be poisoned to death.(in State's aquaculture net was notified to several " calper calcium peroxide causes fresh-water fishes mortality " events).

It can be seen that " ecological balance " there is no being treated as target by current ecological water body processing, but part, it is short-term , not comprehensive decontamination for substance in individual water.It is also able to maintain in ecological water body while effectively eliminating ammonia nitrogen and phosphorus pollution The ecological balance, be that correlative technology field personnel want to solve but can not find always the difficult problems of solution always.This Exactly the utility model technical issues that need to address.

Utility model content

The technical problems to be solved in the utility model is to overcome deficiency in the prior art, is provided a kind of super based on ozone- The ecological water body wisdom managing and control system of sound complex technique.

In order to solve the technical problem, the solution of the utility model is:

It provides a kind of based on ozone-ULTRASONIC COMPLEX technology ecological water body wisdom managing and control system (Water Ecology Intelligent Control and Management System, abbreviation WEICOMS), including what is handled for water body purification Ozone generator and ultrasonic equipment；The system further includes rich phosphorus abatement device, which is equipped with solid for loading calper calcium peroxide The container of body powder or calper calcium peroxide solution, container are equipped with metering valve or metering pump, the outlet and discharge of metering valve or metering pump Pipeline connects；Ozone generator, ultrasonic equipment and rich phosphorus abatement device are arranged at nearby water bodies, the ozone of ozone generator Discharge conduit outlet, the discharge pipe outlet of the energy converter of ultrasonic equipment and rich phosphorus abatement device are respectively positioned in water body；

The system further includes multiple water quality sensors of the arranged for interval in water body, and each water quality sensor is configured with fixed Position chip, algae bio monitor, water quality monitor, NB-iot transmission module and controller module；Positioning chip, algae bio Monitor, water quality monitor and NB-iot transmission module are connected with controller module respectively, and are passed through by NB-iot transmission module NB-iot internet of things realizes that the data between wisdom management control center server are transmitted；Controller module also passes through signal wire point Not Lian Jie the controller of ozone generator, ultrasonic equipment driving power, and metering valve or the metering of rich phosphorus abatement device Pump is respectively used to control ozone occurrence quantity, ultrasonic power and calper calcium peroxide burst size.

As an improvement be equipped in the water quality monitor for monitor the COD of water body, ammonia nitrogen, pH, salinity, temperature, The sensor of current vector and transmission data.

As an improvement the water quality sensor has shape body, at least three sets of the water quality monitor, it is spaced Three fragment position of upper, middle and lower of shape body is set, for monitoring the surface layer, middle layer and bottom water quality of water body.

As an improvement the controller module use ARM device, and be used as local storage device storage card phase Even.

As an improvement the richness phosphorus abatement device is further connected with water inlet pipe, primer pump is housed on water inlet pipe；Water inlet pipe Entrance be located in water body, from water body diversion come wash away calcium oxide solid powder or calper calcium peroxide solution just from discharge pipe arrange Into water body (this is to solve the problems, such as the abnormal rising of bring ammonia nitrogen ratio after phosphorus reduces in water).

As an improvement the wisdom management control center server is the big data cloud computing server system based on cloud System.

Utility model principles illustrated:

1, the process object in the utility model be ecological water body, in particular to " a variety of animals and plants, microorganism and other The water body that substance coexists under certain natural conditions ", it will be appreciated that for waters such as pool, lake, rivers.Ozone and ultrasound all have Very strong oxidative degradation and the effect for killing aquatile and pathogen.If the two is combined for handling with biology The ecological water body of pollution and organic chemistry pollution, the effect of generation not instead of the two acts on simple superposition, mutually with rush Into the synergistic effect of amplification.Because ozone dissolution in water is so that " cavitation effect " of ultrasonic medium enhances, compression- The oscillation of explosion aqueous medium and squeezing action are amplified；Meanwhile ultrasonic wave also improves the oscillation activity of hydrone, reduces molecule Between viscous force, enhancing ozone meltage and solution rate in water.

Ozone-ULTRASONIC COMPLEX technology is depended on using the rich phosphorus abatement technology of calper calcium peroxide, this is the utility model reality Existing ecological water body manages innovative content.So-called depend on refer to, this three must be fitted close could safely, controllably play and remove Phosphorus effect.As described in the background section, rich phosphorus is after by calper calcium peroxide mineralising, and further decomposition and reaction will generate hard to tolerate In water calcium carbonate and release OH-Water pH value is increased, leads to have broken the balance of ammonia nitrogen and phosphorus in ecological water body.Ammonia nitrogen Ratio increases substantially, though it is also no longer to meet biological (especially water body animal) existence that consequence, which is exactly that water body is purified, Ecological water body.It is organically combined by the three technology of the utility model, while eliminating phosphate radical using calper calcium peroxide, is used Ammonia nitrogen in the strong oxidation that ozone-ultrasound generates while water of degrading makes nitrogen and water, can be solved perfectly above-mentioned Problem.

2, the utility model using the population of algae and quantity as the instruction of the ecological balance be with scientific research and practice according to According to:

Algae is no embryo and the autotrophy thallus cryptogam with chlorophyll, belongs to the primary producer of ecological water body That is the first link of food chain is the key node that organic matter, inorganic matter and life entity start substance and Life Cycles.In ecology In water body, algae is throughout each region, and the type composition of algae depends on variety classes to the sensibility of environmental change. Meanwhile distribution of the substances such as organic matter, inorganic matter, metal in ecological water body in ecological water body is with circulation and specifically Property, main separated region has land waterfront, deposit area, water body-Sediment Interface, gap water body, biotic division and Air-Water Body interface.Therefore, the dynamic behaviour of pollutant is influenced by integrated conditions such as water body, gas, biology and deposits.Algae It is water body food web basal nutrient layer, and its distribution and the various substance distributed areas of ecological water body are overlapped, therefore algae can The case where reflecting water ecosystem substance storage and variation at the first time.

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Specifically, be exactly if that a certain algae is more sensitive to certain pollutant, when ecological tree body touches the substance, Sensitive algae is first subjected to influence, and then disappears.In addition, some algae have environmental change caused by certain pollutants Certain tolerance, other algae disappear or after largely reducing, tolerance type still can normal existence or by smaller influence, And become dominant population.In addition to this, relatively large algae has certain absorption enrichment to the important poisonous substance in water body, Composition transfer in these algae fronds of long term monitoring helps to play indicative function to water quality.Therefore, Measures of Algae in Water Body kind is utilized The composition of group, may be implemented the monitoring to water pollutant situation of change.

Compared with prior art, the utility model has the beneficial effects that

1, the utility model is innovatively with " the calper calcium peroxide richness phosphorus abatement combined closely with ozone-ULTRASONIC COMPLEX technology Core function unit of the device " as ecological water managing and control system.While eliminating phosphate radical using calper calcium peroxide, utilization is smelly Ammonia nitrogen in the strong oxidation that oxygen-ULTRASONIC COMPLEX generates while water of degrading makes nitrogen and water, fundamentally prevents water Treatment process generates the ingredient for having negative effect to ecological water system, ensure that the intracorporal ecological balance of ecological water is not broken It is bad.

2, the utility model innovatively utilizes the indicative function of the pairs of water pollutant variation of Measures of Algae in Water Body population group, will The monitoring data for the multiple automatic identification equipments being installed in water body are transmitted to control centre by NB-iot approach, and by big Data cloud computing wisdom decision controls ecological water body Water-quality control equipment running status, with " wisdom feedback-control is in ring " Mode controls water body flow vector, light transmittance, eliminates harmful organic substance, sex pheromone and suspended matter in water, control ammonia nitrogen, Sulphur, phosphorus, carbon dioxide level, and blow down pernicious gas in water, reduce poisonous metal object, increase oxygen content etc. ecological element, Intelligent algorithm termination rules are existed for the population of algae and the reasonable of quantity again, are realized to the real-time complete of the more elements of water ecology It effectively manages in face.

3, the technical route that the utility model uses is not related to using may bring secondary pollution or to the subsequent shadow of environment It rings and acts on suspicious chemical agent.

4, easy to operate, use cost is cheap and logistic work is very simple.Use environment is adaptable, no matter cold Heat or sleet nebelwind weather equipment can operate normally use.

5, occupied area is small, and low energy consumption.Fixed work station or motor driven, half motor-driven workstation mode can be used It is nearby continued working, can also be carried out with motorized transport to different places, adaptation to local conditions with the fixed ecological water body that is built in of equipment Ecological water body control.

6, use scope is wide, and function is strong, it can as the daily maintenance control usually to ecological water body, can also take notice of Emergency is carried out to water body under external environment hazardous condition and strengthens control, such as cyanobacterial bloom outburst, SARS, bird flu, swine flu disease Epidemic disease is popular or artificial harmful organic chemistry material is bled into the particular times such as water accidentally.

7, unit time water treatment capacity can take the circumstances into consideration to manufacture and design from handling more than ten cubic metres per hour to thousands of cubic meters. Relative to traditional more than ten, billions of first water treatment technologies invested easily, reach ozone-ULTRASONIC COMPLEX ecological water of same purpose Body processing technique equipment only has its small a part.

Detailed description of the invention

Fig. 1 is the frame diagram that ecological water body wisdom manages technology.

Specific embodiment

Below with reference to specific embodiment of the utility model, specific embodiment of the present utility model is retouched in detail It states.

As shown in Figure 1, including being used for water body purification based on ozone-ULTRASONIC COMPLEX technology ecological water body wisdom managing and control system The ozone generator and ultrasonic equipment of processing, and rich phosphorus abatement device.Rich phosphorus abatement device is equipped with for loading peroxidating The container of calcium solid powder or calper calcium peroxide solution is equipped with metering valve or metering pump in container bottom, metering valve or metering pump Outlet connects with discharge pipe；In view of the effect that feeds, rich phosphorus abatement device is further connected with water inlet pipe, and diversion is housed on water inlet pipe Pump；The entrance of water inlet pipe is located in water body, from water body diversion come wash away calcium oxide solid powder or calper calcium peroxide solution just from Discharge pipe drains into water body；The water flow of circulation can also form circulative convection in water body, reinforce purified treatment effect.Ozone Generator, ultrasonic equipment and rich phosphorus abatement device are arranged at nearby water bodies, the ozone discharge conduit outlet of ozone generator, The discharge pipe outlet of the energy converter of ultrasonic equipment and rich phosphorus abatement device, which is respectively positioned in water body, (only to be shown rich phosphorus to disappear in figure Subtract the water inlet pipe and discharge pipe of device)；In the utility model, commercial product (example is can be used in ozone generator, ultrasonic equipment As the ozone generator of woods environmental protection Science and Technology Co., Ltd., Qingdao state production, Hangzhou Success Ultrasonic Equipment Co., Ltd produce Ultrasonic equipment).Rich phosphorus abatement device can be made by oneself, can also purchase commercially available components and be assembled.

The system further includes multiple water quality sensors of the arranged for interval in water body, and each water quality sensor is configured with fixed Position chip, algae bio monitor, water quality monitor, NB-iot transmission module and controller module；Water quality sensor has bar Shape main body, is arranged at intervals on three fragment position of upper, middle and lower of shape body, for monitoring water body by least three sets of water quality monitor Surface layer, middle layer and bottom water quality.Positioning chip, algae bio monitor, water quality monitor and NB-iot transmission module respectively with Controller module be connected, and by NB-iot transmission module by NB-iot internet of things realize with wisdom management control center server it Between data transmission；Controller module also passes through the drive that signal wire is separately connected the controller of ozone generator, ultrasonic equipment Dynamic power supply, and the metering valve or metering pump of rich phosphorus abatement device, are respectively used to control ozone occurrence quantity, ultrasonic power and mistake Calcium oxide burst size.Wisdom management control center server can be the big data cloud computing server system based on cloud (can also be with It is the remote server positioned at user local).

Example is applied in this conduct, and GPS or Beidou positioning chip can be selected in the positioning chip；Algae bio monitor can be adopted The AlgaeC multifunctional bio monitor algae counts intelligence produced with commercial product, such as the gloomy detection Science and Technology Ltd. in Hangzhou ten thousand Assessing instrument.COD, ammonia nitrogen, pH, salinity, temperature, current vector and the light transmission degree for monitoring water body are equipped in water quality monitor According to sensor, these sensors can purchase commercial product.NB-iot transmission module is wide with covering, connection is more, rate is low, At low cost, the low in energy consumption, features such as framework is excellent, are very suitable to the transmission of monitoring data, can be used Shanghai Yi Yuan company Quectel's BC95；Controller module can be used ARM device, and with the storage card (such as the G byte, T byte large capacity that are used as local storage device Removable store equipment) be connected, data in storage card will be as backing up and retrospect initial data foundation.

Ozone based on aforementioned system-ULTRASONIC COMPLEX technology ecological water body wisdom management-control method, comprising the following steps:

(1) in the waters appropriate positions near setting ozone generator of control to be administered, ultrasonic equipment and rich phosphorus abatement Device exports the ozone discharge conduit of ozone generator, the delivery pipe of the emitting head of ultrasonic equipment and rich phosphorus abatement device Way outlet is located in water body；

(2) the one or more groups of water quality sensors of arranged for interval in the waters of control to be administered, every suit ozone generator, Ultrasonic equipment and rich phosphorus abatement device match with one group of (or several groups) water quality sensor, include in every group of water quality sensor Multiple water quality sensors；Rod-shaped water quality sensor bottom is inserted into the mud of water bottom and keeps firm, senses water quality Water quality monitor on device can detect the water quality of water body surface layer, middle layer and bottom respectively；

(3) water quality sensor utilizes positioning chip, algae bio monitor and the water quality monitor of its configuration, obtains current Alga classifying identification in time and location data, water body and the COD in enumeration data and water body, transparency, coloration, contain Oxygen, sulphur, phosphorus, ammonia nitrogen data；After the data of acquisition are stored in storage card by controller module, passed through by NB-iot transmission module NB-iot internet of things is transmitted to wisdom management control center server；

(4) after the data of wisdom management control center server reception each group water quality sensor, data are carried out according to pre-defined rule Arrangement and comparison (that is, by each water quality sensor water quality monitor obtain data and and algae bio monitor obtain Data preparation be specified parameter specification, then it is compared with the default control index of projects), pass through NB-iot Internet of things sends manipulation instruction to specified water quality sensor；The controller module of water quality sensor is according in manipulation instruction Hold, sends control signal to ozone generator, ultrasonic equipment or rich phosphorus abatement device respectively, pass through the control to ozone generator The driving power of device processed, ultrasonic equipment, and the metering valve or metering pump of rich phosphorus abatement device are regulated and controled, and realize ozone hair The control of raw amount, ultrasonic power and calper calcium peroxide burst size；

(5) each group water quality sensor monitors in real time and into wisdom management control center server transmission regulation process in water body All data, by wisdom management control center server according to pre-defined rule change manipulation instruction, by gradually adjust ozone occurrence quantity, Ultrasonic power and calper calcium peroxide burst size control the abatement speed of water pollutant, reduce the local detection data of projects Difference between pre-set level finally makes all data of water body meet expected control target.

In the utility model, settable two sets of wisdom management control center server or more industrial computers mutually backup, and every set can There are more, signaling and makes wisdom decision, persistence and constantly substantial large database concept and its standby for controlling/coordinating all quarters concerned Part.Industrial computer can incorporate entire ecological water body managing and control system as server by network, become in feedback-control Pivot carries out long-range wisdom control to ecological water body processing equipment, the water quality situation of report and early warning ecological water body, and with it is more advanced The computer at other big data cloud computing wisdom control center is communicated, meet higher level's computer gathering information, participative decision making, Expand large database concept etc. to require.

Specific to the operation of ecological water body Water-quality treater, entire workflow is just controlled by industrial computer --- diversion Pump is driven by frequency converter, and the water that can adjust unit time processing (is received by frequency converter by RS485 bus access industrial computer Instruction), dosage, ozone output, the power of ultrasonic device, ancillary equipment (such as filter device or water circulation of calper calcium peroxide With bubbling device) operation instruction is all received by RS485 bus access industrial computer by PLC, with multi gear position adjust output effect Can, to meet the controllable requirement of the more elements of ecological water body.

Responsibility and pressure of the managers at different levels from spirit to physical strength can be greatly reduced in ecological water body wisdom formula managing and control system Power avoids the awkward situation of " work cannot be implemented and be accomplished to bottom " common in efforts at environmental protection, avoids general long-range monitoring The constraint of " situation report can be received but be difficult to work hard to change the status quo ".Meanwhile crew numbers and spending are also reduced, Avoid management organization's internal responsibility it is indefinite caused by administration and technical resource utilization efficiency it is not high.Because ecological water body is renovated It has been assumed responsibility for via ecological water body wisdom formula managing and control system " voluntarily " with the responsibility of maintenance, and not ecological water body It manages also eternal to a satisfied level.This is the operation mould of " process link correctly causes final job performance correct " Formula.It can be seen that single ecological water quality wisdom managing and control system does not answer individualism with the development of work, it this be Geng great Qu One component part of domain ecological replacement managing and control system --- this " bigger " system also will be " bigger " ecological water body wisdom The component part of managing and control system, it is final to realize that --- zonule small group --- single from single-point big big area data of group is shared Highly-specialised, clustering and the scientific ecological water body wisdom formula managing and control system of socialization.

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